My ISP has blocked port 25 and we need to use it to verify emails using atomic email hunter. Which service should we choose to verify emails?

If you are trying to send outbound emails and your ISP blocks port 25, use Outbound SMTP relay service at https://www.dynu.com/en-US/Email/Outbound-SMTP-Relay. If it is for receiving emails, use email store/forward service.